Course - Electrochemistry - TMT4252
TMT4252 - Electrochemistry
Examination arrangement: School exam
|Evaluation||Weighting||Duration||Grade deviation||Examination aids|
|School exam||100/100||4 hours||C|
Electric potentials and fields. Conductivity and capacitance. Thermodynamics of aqueous solutions: Activities and the Debye-Hückel-model. Electrolysis cells and galvanic cells with and without transfer. Potential differences across Liquid junctions. Electrosynthesis of metals and chemicals, electrodialysis and salt splitting. UN goals for sustainable development: Electrochemical energy storage in hydrogen and batteries. Fuel cells. Electrodes and electrode reactions. Electrode kinetics: Current-voltage characteristics of charge-transfer reactions. Reaction order. Transport processes and mass transfer coefficients. Green electrochemistry and UN goals for sustainable development: Electrochemistry in analysis of the environment and environmental remediation. Electrochemical description of biological cells. Transport-, activation- and ohmic overpotential. The electrochemical double layer in brief. Demonstration of a rotating electrode and a potensiostat.
Upon course completion the student is able to - define central parts of electrochemical cells and electrochemical equipment such as anode, cathode, membrane, diaphragm, liquid junction, reference electrode, and potentiostat - define and relate mathematically basic physical and thermodynamic concepts related to electrochemical cells such as electric potential, electric field, cell potential, null potential, electrochemical potential, and activity - account for sign conventions - account for the electrochemical series and representation of electrochemical thermodynamics in Pourbaix diagrams - define and describe mathematically diffusion, migration, and convection -define transport, kinetic and ohmic overpotential -calculate the combined transport and kinetic overpotential for electrodes at which a one-electron reaction takes place and for which transport can be described through mass transfer coefficients - calculate ohmic overpotential for dilute solutions for macro- and microelectrodes such as trough electrodes, hemispherical electrodes, and disk electrodes - calculate Tafel slopes and reaction orders for multiple-step electrochemical reactions in the absence of transport limitations - calculate liquid-junction and membrane potentials in simple cases - analyze a given electrochemical cell or experiment, judge to which extent the approximations underlying the above equations apply, and explain and predict quantitatively the outcome for cases in which they do - describe the structure of the electrified interface, and define and describe mathematically the capacitance of the Helmholz layer - give an overview of applications of electrochemistry in synthesis and purification of materials and chemicals, energy storage, biology, and analysis and remediation of the environment, and provide a description of selected processes within these areas
Learning methods and activities
Lectures and exercises. 2/3 of the exercises must be approved to qualify for the exam. The problem sets include training in use of digital tools for simulation of electrochemical processes. During the course an excursion to visit electrochemical industries may be arranged. The total workload is 200 hours.
- Midt term
Further on evaluation
Access to the final examination on the condition that the mid-term test has been passed and that 2/3 of the problem sets have been approved. If there is a re-sit examination, the examination form may be changed from written to oral.
Compulsory activities from previous semester may be approved by the department.
Recommended previous knowledge
Basic knowledge of chemistry and physics corresponding to TMT4110 Chemistry, TMT4115 General Chemistry and TMT4120/TFY4104 Physics. A basic knowledge of engineering mathematics corresponding to TMA4100 Mathematics 1, TMA4105 Mathematics 2, and TMA4115 Mathematics 3.
K. B. Oldham, J. C. Myland, and A. B. Bond, Electrochemical Science and Technology, John Wiley & Sons, Chichester (2012), ISBN 978047071045 (PB). Also availabele as e-book and in HB.
Credits: 7.5 SP
Study level: Second degree level
Term no.: 1
Teaching semester: SPRING 2022
Language of instruction: English, Norwegian
- Materials Science and Engineering
- Technological subjects
Examination arrangement: School exam
- Term Status code Evaluation Weighting Examination aids Date Time Examination system Room *
- Spring ORD School exam 100/100 C 2022-06-08 09:00 INSPERA
Room Building Number of candidates
- * The location (room) for a written examination is published 3 days before examination date. If more than one room is listed, you will find your room at Studentweb.
For more information regarding registration for examination and examination procedures, see "Innsida - Exams"